Topic: Coordination Compounds, Test No.: 05, Total MCQs: 10
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Question 1 |
Which one of
the following complex ions has geometrical isomers?
[Cr (NH3)4
(en)]3+ | |
[Co (en)3]3+ | |
[Ni (NH3)5
Br]+ | |
[Co (NH3)2
(en)2]3+ |
Question 2 |
Which one of the following cyano complexes would exhibit the lowest value of paramagnetic behaviour?
(At. No. Cr = 24, Mn = 25, Fe = 26, Co = 27)
[Cr(CN)6]3– | |
[Mn(CN)6]3– | |
[Fe(CN)6]3– | |
[Co(CN)6]3– |
Question 3 |
Which one of the following has a square planar geometry? (At. Nos. Co = 27, Ni = 28, Fe = 26, Pt = 78)
[CoCl4]2– | |
[FeCl4]2– | |
[NiCl4]2– | |
[PtCl4]2– |
Question 4 |
Which one of the following has an optical
isomer?
(en = ethylenediamine)
[Zn(en)(NH3)2]2+ | |
[Co(en)3]3+ | |
[Co(H2O)4(en)]3+ | |
[Zn(en)2]2+ |
Question 5 |
Which kind of
isomerism is exhibited by octahedral Co(NH3)4Br2Cl?
Geometrical and ionisation | |
Geometrical and optical | |
Optical and ionisation | |
Geometrical only |
Question 6 |
Which of the following compounds shows optical
isomerism?
[Cu(NH3)4]2+ | |
[ZnCl4]2– | |
[Cr(C2O4)3]3– | |
[Co(CN)6]3– |
Question 7 |
Which of the
following facts about the complex [Cr(NH3)6]Cl3
is wrong?
The complex gives white precipitate with silver nitrate solution | |
The complex
involves d2sp3 hybridization and is octahedral in shape | |
The complex is paramagnetic | |
The complex is an outer orbital complex |
Question 8 |
Which of the
following has an optical isomer?
[Co(NH3)3
Cl]+ | |
[Co(en) (NH3)2]2+ | |
[Co(H2O)4
(en)]3+ | |
[Co(en)2
(NH3)2]3+ |
Question 9 |
Which of the following pairs represents linkage
isomers?
[Pd(P Ph3)2 (NCS)2] and
[Pd(P Ph3)2(SCN)2] | |
[Co (NH3)5 NO3]SO4
and [Co(NH3)5SO4] NO3 | |
[Pt Cl2(NH3)4]Br2
and [PtBr2(NH3)4]Cl2 | |
[Cu(NH3)4] [PtCl4] and
[Pt(NH3)4] [CuCl4] |
Question 10 |
Which of the
following statements is incorrect?
In K4
[Fe(CN)6], the ligand has satisfied both primary and secondary
valencies of ferrous ion. | |
In [Cu(NH3)4]SO4,
the ligand has satisfied only the secondary valency of copper. | |
In K3[Fe(CN)6]
, the ligand has satisfied only the secondary valency of ferric ion. | |
In K3[Fe(CN)6],
the ligand has satisfied both primary and secondary valencies of ferric ion. |
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